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Stark Spectroscopy of Mixed-Valence Systems
Stark spectroscopy reaction centre mixed valence intervalence charge transfer Creutz–Taube ion
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2016/5/25
Many mixed-valence systems involve two or more states with different electric dipole moments whose magnitudes depend upon the charge transfer distance and the degree of delocalization; these systems c...
Electrostatic and Conformational Effects on the Electronic Structures of Distortional Isomers of a Mixed-Valence Binuclear Cu Complex
Electrostatic Conformational Electronic Structures Distortional Isomers Mixed-Valence Binuclear Cu Complex
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2016/5/23
The electronic structure of the binuclear copper complex [Cu(2)(L)](3+) [L = N(CH(2)CH(2)N(H)CH(2)CH(2)N(H)CH(2)CH(2))(3)N] has been investigated by resonance Raman and electroabsorption spectroscopy....
Effective Charger Transfer Distances in Mixed-Valence Transition Metal Complexes
Charger Transfer Distances Mixed-Valence Transition Metal Complexes
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2016/5/23
Stark (electroabsorption) spectroscopy can provide quantitative information on the change in dipole moment and polarizability for an electronic transition. In the case of mixed-valence transitions, th...
Electrochromism in the Near-Infrared Absorption Spectra of Bridged Ruthenium Mixed-Valence Complexes
inorganic, organic, physical and analytical chemistry ruthenium complexes absorption spectra electrochromism electric fields experimental data low temperature measuring methods near infrared radiation complexes
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2016/5/23
Many experimental and theoretical approaches have been developed to characterize the chemical and physical properties of mixed-valence complexes. These molecules may possess metals in differing oxidat...
Electronic Coherence in Mixed-Valence Systems: Spectral Analysis
Electronic Coherence in Mixed-Valence Systems Spectral Analysis
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2014/9/24
The electron transfer kinetics of mixed-valence systems is studied via solving the eigenstructure of the twostate nonadiabatic diffusion operator for a wide range of electronic coupling constants and ...
An adiabatic picture for electron transfer in mixed-valence systems
An adiabatic picture electron transfer mixed-valence systems
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2014/9/24
An adiabatic picture is proposed to analyze short-time electronic coherence and dephasing in mixed-valence systems,which cannot be described by the Redfield equation or the golden-rule rate theory. In...